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A Gaussian-2 molecular orbital study of the sigmatropic 1,3-hydrogen shift in 1-silapropene

โœ Scribed by Suk Ping So

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
325 KB
Volume
254
Category
Article
ISSN
0009-2614

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Direct measurements of the rates of 1,3-
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โœ Tadashi Arai; Seiji Tobita; Haruo Shizuka ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 513 KB

The rate constants for the 1,3-and 1,Mgmatropic hydrogen shifts of the phot&Fries rearranged intermediates of phenyl acetate produced by laser flash photolysis at 266 nm were directly measured in several solvents. The rate constant for the 1,3hydrogen shift (3.6 s-l) was faster than that for the l&s