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An Investigation of Structural Stability and Internal Rotation in 3-Cyclopropenecarboxaldehyde and 3-Cyclopropenecarboxylic Acid Fluoride by ab initio Calculations

✍ Scribed by HassanM. Badawi; Wolfgang Förner; AliA. Al-Rayyes

Publisher
Springer-Verlag
Year
1998
Tongue
English
Weight
102 KB
Volume
4
Category
Article
ISSN
1610-2940

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The microwave spectrum of (CH 3 ) 3 SiCl and its isotopic species (CH 3 ) 3 Si 37 Cl, (CH 3 ) 3 29 SiCl, (CH 3 ) 3 30 SiCl, and ( 13 CH 3 )(CH 3 ) 2 SiCl has been studied in the frequency range of 3 to 40 GHz. The barrier to internal rotation, the chlorine quadrupole coupling, and the structure were