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An investigation of anodes for the oxidation of manganate (VI) to manganate (VII)

โœ Scribed by P. Cox; D. Pletcher; R.P.S. Saluja

Book ID
107749949
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
479 KB
Volume
36
Category
Article
ISSN
0013-4686

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๐Ÿ“œ SIMILAR VOLUMES

Anomalously large effects of pressure on
Anomalously large effects of pressure on electron transfer kinetics in solution: The aqueous manganate(VI)-permanganate(VII) system
โœ T.W. Swaddle; L. Spiccia ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science โš– 254 KB

The classical Stranks-Hush-Marcus theory of pressure effects on the rates of outer-sphere electron transfer reaction rates in solution underestimates IzaV\*[; specifically, for the MnO4/MnO24 (aq) exchange, zaV\*=-21.2 (observed) vs. -6.6cm 3 mol 1 (calculated). This discrepancy can best be resolved