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An intramolecular anionic fries rearrangement of N-acylphenothiazines

✍ Scribed by Anders Hallberg; Arne Svensson; Arnold R. Martin

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 201 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84421-4

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✦ Synopsis

Z-substituted N-acylphenothiazines undergo a rapid intramol&ular N+c migration on reaction with lithium N,N-dialkylamides at -780. Preliminary studies of the Scope and mechanism

of this anionic version of the Fries rearrangement are reported.

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