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An Interesting AlEt3-Promoted Stereoselective Tandem Rearrangement/Reduction of α-Hydroxy (or Amino) Heterocyclopropane.

✍ Scribed by Xin Li; Bin Wu; Xue Zhi Zhao; Yan Xing Jia; Yong Qiang Tu; De Run Li

Publisher
John Wiley and Sons
Year
2003
Weight
110 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

📜 SIMILAR VOLUMES

A Novel Strategy for the Key Fully Subst
A Novel Strategy for the Key Fully Substituted Cyclopentenedione Moiety of Madindolines via AlEt3-promoted Tandem Reductive Rearrangement of α-Hydroxy Epoxides
✍ Shuan-Hu Gao; Yan-Xing Jia; Xue-Zhi Zhao; Yong-Qiang Tu 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 51 KB

## Abstract The fully substituted cyclopentenedione core of madindoline A (**1**) and B (**2**) as potent and selective inhibitor of IL‐6 has been synthesized efficiently. The quaternary carbon center C‐2′ was constructed on the basis of a newly developed AlEt~3~‐promoted tandem reductive rearrange