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An inhibitor of reverse transcriptase in the cytoplasm of the cultured cells and the spleen of mice

โœ Scribed by Makoto Rokutanda; Yukiko Y. Maeda; Sumiyo T. Watanabe

Book ID
115755551
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
344 KB
Volume
108
Category
Article
ISSN
0006-291X

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An enantioselective synthesis of the core unit of the non-nucleoside reverse transcriptase inhibitor taurospongin A
โœ Arun K. Ghosh; Hui Lei ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 128 KB

An enantioselective formal synthesis of taurospongin A has been achieved. The key steps involve chelation-controlled reductions of ฮฒ-ketosulfoxide and ฮฒ-hydroxy ketone intermediates and Sharpless asymmetric epoxidation to construct the tertiary alcohol stereoselectively.