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An infrared spectroscopic study of the phase transitions of crystalline aromatic donor—acceptor complexes involving a pseudoplastic state

✍ Scribed by H.Ramachandra Swamy; Somnath Ganguly; C.N.R. Rao

Book ID
103907212
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
383 KB
Volume
39
Category
Article
ISSN
1386-1425

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✦ Synopsis

Variable temperature i.r. spectroscopic studies of weak x-donor-n-acceptor complexes in the crystalline state indicate that the complexes undergo orderdisorder transitions, the disorder being caused by molecular motion. Thermodynamicdata on the phase transitions along with the spectral data suggest that the high-temperature crystalline forms of the complexes are likely to be pseudoplastic.

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