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An Improved Synthesis of 1,3,3-Trimethyl-2-azabicyclo[2.2.2]octane and Its Nitroxyl Radical Product, a Rigid Analogue of TEMPO

✍ Scribed by Bakunov, Stanislav ;Tkachev, Alexey

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 246 KB
Volume: 1997
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199719970740

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✦ Synopsis

Abstract

A new synthetic approach for the production of isoquinuclidine 6 from dipentene (rac‐limonene, 1) is described. The nitroxyl 5, a rigid analogue of TEMPO, has been prepared from 6 in 87% yield.

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