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An improved procedure for the detritylation of 1-alkyl 2-acyl 3-trityl-sn-glycerols

✍ Scribed by Takashi Iwama; Thomas A. Foglia


Book ID
112777757
Publisher
Springer-Verlag
Year
1988
Tongue
English
Weight
547 KB
Volume
65
Category
Article
ISSN
0003-021X

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An improved method for the preparation o
✍ HansjΓΆrg Eibl πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 258 KB

A simple and fast route for the preparation of 1,2-isopropylidene-sn-glycerol from Dmannitol in 45% yield is described. The value of optical rotation, [a] ~ + 15.2 Β°, is higher than usual indicating considerable racemization for other procedures, Since 1,2-isopropylidene-sn-glycerol serves as genera