An improved method for the determination of cross-relaxation rates from NOE data
β Scribed by S Macur; B.T Farmer II; L.R Brown
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 400 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0022-2364
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract An efficient method of measuring proton spinβlattice crossβrelaxation rates in small molecules is proposed. The method involves measuring the difference in relaxation rates in a nonβselective experiment and in one with all resonances except one of interest inverted. This procedure yield
To evaluate chemical relaxation data for an assumed single-step mechanism of the type k12 E+ST ES, linear regression methods are usually applied to the equation describing the concentration dependence of the relaxation time t, l/r = /c&G] + [$I) + k2,. Since calculated values of [,!?I and [s] depend