𝔖 Bobbio Scriptorium
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An Improved and Facile Preparation of ω-SF5-(Perfluoroethyl)benzene (SF5CF2CF2C6H5).

✍ Scribed by R. W. Winter; G. L. Gard


Publisher
John Wiley and Sons
Year
2003
Weight
85 KB
Volume
34
Category
Article
ISSN
0931-7597

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Fluoroborates by Cleavage of Trimethylam
✍ David J. Brauer; Hans Bürger; Regina Hübinger; Gottfried Pawelke 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 183 KB 👁 1 views

Trimethylamine-bis(trifluoromethyl) boranes R(CF 3 ) 2 B ´NMe 3 (R = cis/trans-CF 3 CF=CF (1/2), HCºC (3), H 2 C=CH (4), C 2 H 5 (5), C 6 H 5 CH 2 (6), C 6 F 5 (7), C 6 H 5 (8)) react with NEt 3 ´3 HF depending on the nature of R at 155±200 °C under replacement of the trimethylamine ligand to form