๐”– Bobbio Scriptorium
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An Improved and Efficient Method for Diazo Transfer Reaction of Active Methylene Compounds

โœ Scribed by Lee, Jong Chan; Yuk, Jong Yeob


Book ID
120413658
Publisher
Taylor and Francis Group
Year
1995
Tongue
English
Weight
156 KB
Volume
25
Category
Article
ISSN
0039-7911

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Without prior activation of allyl alcohols, allylation of a variety of active methylene compounds with allyl alcohols proceeds smoothly at rt -508C in the presence of catalytic amounts of Pd(OAc) 2 (1 -10 mol%), Et 3 B (30 -240 mol%), a phosphine ligand (1 -20 mol%), and a base (0 to 50 -60 mol%).