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An Extension of the Marcus Equation for Atom Transfer Reactions

✍ Scribed by Blowers, Paul; Masel, Richard I.

Book ID
120481248
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
145 KB
Volume
103
Category
Article
ISSN
1089-5639

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The rate constants for reaction of a series of Re(CO),L (L=CO, PR3, P(OR),) radicals with various -atom or functional group donors in hexane at room temperature have been measured using laser flash photolysis. The data in each series have been analyzed in terms of the linear free energy relationship