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An experimentally derived torsional potential function for HSSH

✍ Scribed by Eric Herbst; Gisbert Winnewisser

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 384 KB
Volume: 155
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)87475-5

No coin nor oath required. For personal study only.

✦ Synopsis

A variety of milimeter-wave and far-infrared spectral data on the internal rotor HSSH has been used to determine the cis and tram barrier heights to torsional motion. Our values of 2800( ) and I990( 15) cm-' for V,,, and V,,,,,, respectively, are in good agreement with the results of ab initio calculations.

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