A configuration interaction calculation, using model potential methods, is employed to evaluate the energy of the lowest 'S state of Li-. The model potential describing the valence electron-core interaction is chosen so as to reproduce the obserxd :,~&a of the neutral lithium atom with high precisio
โฆ LIBER โฆ
An experimental estimate of the electron affinity of lithium
โ Scribed by B. Ya'akobi
- Publisher
- Elsevier Science
- Year
- 1966
- Weight
- 187 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0031-9163
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In qualitative agreement with semi-empirical (MNDO) and ab initio calculations, the electron affinities measured by electron transmission spectroscopy are found to be strongly negative for allene (-1.9 -+ 0.1 eV) and propyne (-2.8 -+ 0.1 eV)