An expeditious route to carbocyclic nucleosides: (−)-aristeromycin and (−)-carbodine
✍ Scribed by Fabienne Burlina; Alain Favre; Jean-Louis Fourrey; Martial Thomas
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 251 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0960-894X
No coin nor oath required. For personal study only.
✦ Synopsis
The readily available bicyclic lactone (-)-1 was transformed into diacetate (-)-2 which served in an expeditious route to (-)-aristeromycin (3a) and (-)-carbodine (3b) in acceptable yields.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Benzocycloheptenones photoisomerise to strained transbenzocycloheptenones which undergo smooth /-4+2 7 cycloaddition with a variety of dienes. The adducts with cyclopentadiene can be readily transformed to trans fused 5-7-6 ring systems while cycloaddition with isoprene and 2-trimethylsilyloxy-l,3-