✦ LIBER ✦

Palladium-assisted route to carbocyclic nucleosides: A formal synthesis of (±)-aristeromycin

✍ Scribed by Donald R Deardorff; Michael J Shulman; James E Sheppeck II

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 266 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)70635-6

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A convenient route to carbocyclic analog

A convenient route to carbocyclic analogs of nucleosides: (±) aristeromycin

✍ Anil K. Saksena 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 261 KB

ChemInform Abstract: An Expeditious Rout

ChemInform Abstract: An Expeditious Route to Carbocyclic Nucleosides: (-)-Aristeromycin and (-)-Carbodine.

✍ F. BURLINA; A. FAVRE; J.-L. FOURREY; M. THOMAS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

Enantiomerically pure chiral building bl

Enantiomerically pure chiral building blocks for syntheses of carbocyclic nucleoside analogues: A formal synthesis of aristeromycin

✍ Helmchen, Günter ;Krotz, Achim ;Neumann, Hans-Peter ;Ziegler, Manfred L. 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 521 KB

## Abstract (+)‐(1__R__,4__R__)‐Bicyclo[2.2.1]hept‐5‐en‐2‐one (7) was prepared in 78.5% yield by oxidative degradation of (+)‐(1__R__)‐__endo__‐bicyclo[2.2.1]hept‐5‐ene‐2‐carboxylic acid (4) by using an improved procedure for the oxidation of the dianion of 4 with dioxygen. Dihydroxylation of 7 wit

ChemInform Abstract: Carbocyclic Nucleos

ChemInform Abstract: Carbocyclic Nucleoside Analogues. Part 1. Concise Enantioselective Synthesis of Functionalized Cyclopentanes and Formal Total Synthesis of Aristeromycin.

✍ S. J. BOYER; J. W. LEAHY 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

A slightly shorter route to carbocyclic

A slightly shorter route to carbocyclic nucleosides. Synthesis of (±)-trans-1-[2-(hydroxymethyl)cyclopentylmethyl]uracil

✍ Lourdes Santana; Marta Teijeira; Eugenio Uriarte 📂 Article 📅 1999 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 186 KB

(土)-trans-1-[2-(Hydroxymethyl)cyclopentylmethyl]uracil (1) was prepared in two steps and \(56 \%\) yield from 2-hydroxymethylcyclopentylmethylamine (7) and 3-methoxy-2-propenoylisocyanate (6). Isocyanate 6 was prepared from methyl 3-methoxy-2-propenoate in four steps and \(38 \%\) overall yield.

ChemInform Abstract: A Slightly Shorter

ChemInform Abstract: A Slightly Shorter Route to Carbocyclic Nucleosides. Synthesis of (.+-.)-trans-1-[2-(Hydroxymethyl)cyclopentylmethyl]uracil.

✍ Lourdes Sanatana; Marta Teijeira; Eugenio Uriarte 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

A Slightly Shorter Route to Carbocyclic Nucleosides. Synthesis of (±)-trans-1-[2-(Hydroxymethyl)cyclopentylmethyl]uracil. -Nucleoside analogue (VIII) is synthesized by constructing the uracil base around the amino alcohol precursor (VI). Isocyanate (V) is equally suitable for formation of the base