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AN EXPEDITIOUS ROUTE TO 7α-SUBSTITUTED ESTRADIOL DERIVATIVES

✍ Scribed by Rosanna Tedesco; John A Katzenellenbogen; Elio Napolitano

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
452 KB
Volume
38
Category
Article
ISSN
0040-4039

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An efficient route to 3-(hydroxymethyl)cyclobutanone acetals via a [2+2] cycloaddition reaction is reported. The dramatic effect of different diol acetals on benzyl deprotection is discussed. Efficient synthesis of two synthetically useful intermediates, 3-methylenecyclobutanone acetal and 3-(bromom