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An expeditious, bidirectional synthesis of furofuranones: a new application of Morita–Baylis–Hillman adducts

✍ Scribed by Goverdhan Mehta; Bilal Ahmad Bhat; T.H. Suresha Kumara

Book ID
108285696
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
418 KB
Volume
50
Category
Article
ISSN
0040-4039

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In this Letter, we describe an easy and straightforward strategy for the preparation of acyloins (a-hydroxyketones) from Morita-Baylis-Hillman adducts, based on a Curtius rearrangement. Different acyloins were obtained with good overall yield (>40% for three steps). To exemplify the synthetic useful