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An Expeditious Assembly of 3,4-Benzannulated 8-Oxabicyclo[3.2.1]octane Systems by [2+2+2] Alkyne Cyclotrimerisation: Total Synthesis of (–)-Bruguierol A

✍ Scribed by Chepuri V. Ramana; Sumanth R. Salian; Rajesh G. Gonnade

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
220 KB
Volume
2007
Category
Article
ISSN
1434-193X

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✦ Synopsis

Abstract

Facile construction of benzene‐fused 8‐oxabicyclo[3.2.1]octane systems by employing a cross alkyne cyclotrimerisation reaction was explored. With this procedure, (–)‐bruguierol A was synthesised, and its absolute configuration was established. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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