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An Expeditious Assembly of 3,4-Benzannulated 8-Oxabicyclo[3.2.1]octane Systems by [2+2+2] Alkyne Cyclotrimerisation: Total Synthesis of (–)-Bruguierol A (Eur. J. Org. Chem. 33/2007)

✍ Scribed by Chepuri V. Ramana; Sumanth R. Salian; Rajesh G. Gonnade

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 284 KB
Volume: 2007
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200790088

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An Expeditious Assembly of 3,4-Benzannul

An Expeditious Assembly of 3,4-Benzannulated 8-Oxabicyclo[3.2.1]octane Systems by [2+2+2] Alkyne Cyclotrimerisation: Total Synthesis of (–)-Bruguierol A

✍ Chepuri V. Ramana; Sumanth R. Salian; Rajesh G. Gonnade 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 220 KB

## Abstract Facile construction of benzene‐fused 8‐oxabicyclo[3.2.1]octane systems by employing a cross alkyne cyclotrimerisation reaction was explored. With this procedure, (–)‐bruguierol A was synthesised, and its absolute configuration was established. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451

ChemInform Abstract: An Expeditious Asse

ChemInform Abstract: An Expeditious Assembly of 3,4-Benzannulated 8-Oxabicyclo[3.2.1]octane Systems by [2 + 2 + 2] Alkyne Cyclotrimerization: Total Synthesis of (-)-Bruguierol A.

✍ Chepuri V. Ramana; Sumanth R. Salian; Rajesh G. Gonnade 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 38 KB