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An Expected Calcium Carbido Borate Chloride: Ca9Cl8(BC2)2

✍ Scribed by Olaf Reckeweg; Francis J. DiSalvo; H.-Jürgen Meyer


Book ID
101306104
Publisher
John Wiley and Sons
Year
1999
Tongue
German
Weight
103 KB
Volume
625
Category
Article
ISSN
0372-7874

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A new chloride-silicate, "belinite", CasMg(Si04)4CI2, has been synthesized from a CaCI o flux. It crystalllzes in perfect octahedra (monoerysta~s). The structure determination revealed cubic symmetry, a = 15.084 ~, space group Fd~. Si-and Mg-atoms are tetrahedrally surrounded by oxygen, Ca occurs in