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An evaluation of rate data for the reactions of atomic Oxygen (O3P) with methane and ethane

✍ Scribed by John T. Herron


Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
557 KB
Volume
1
Category
Article
ISSN
0538-8066

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✦ Synopsis


This review presents in tabular and graphical form rate data on the reactions of atomic oxygen (03P) with methane and ethane. The reliability of these data is discussed and suggested values of the rate constants are given over specified temperature intervals. Specific values are given for 298 and 1000'K.

* Contribution of the National Bureau of Standards, not subject to Copyright.


πŸ“œ SIMILAR VOLUMES


The reaction of atomic oxygen O(3P) with
✍ Steven P. Jewell; Kenneth A. Holbrook; Geoffrey A. Oldershaw πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 330 KB πŸ‘ 2 views

## Abstract The reaction of O(^3^__P__) atoms with isobutane has been studied by using the discharge‐flow system described previously [1]. The rate constant was measured from determinations of the isobutane concentration in the presence of an excess of O atoms and is given by __k__~1~ = (7.9 Β± 1.4)

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## Abstract The reaction of O(^3^__P__) atoms with propanehas been studied at temperatures near 300 K by using a discharge flow system. Oxygen atoms were generated in the absence of molecular oxygen by the reaction N + NO β†’ N~2~ + O, nitrogen atoms having been generated in a microwave discharge. Ra

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The O(3P) + CION reaction has been studicd in a fast flow system over the temperature range from 213 to 295 K, using the air-aftereIow technique for the detection of oxygen atoms under pseudo first order conditions. A value of (3.4 z 0.6) x 10-" exp[(-840 + 60)/T] cm3 molecule-' s-' has been obtaine

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✍ Raymond D. H. Brown; Ian W. M. Smith πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 680 KB

## Abstract Earlier work on the reactions of O(^3^P) atoms with HCl and HBr has been extended by measuring rate constants for equation image A flow‐tube method was used with chemiluminescent monitoring of the removal of atomic oxygen. Rate constants were measured at temperatures between 340 and 4

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## Abstract A flow tube method has been used to determine rate constants for the elementary reactions: equation image Oxygen atoms were produced by adding a small excess of NO to a stream of partially dissociated nitrogen, and their reaction with hydrogen halide was monitored by observing the int

Rate constants for the reactions of O(3P
✍ Dongmin Luo; John A. Pierce; Irina L. Malkina; William P. L. Carter πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 543 KB

## ~~ ~ Rate constants for the gas-phase reactions of O(3P) atom with a series of rnonoterpenes have been determined at ambient temperature (ca. 302-309 K ) and atmospheric pressure using a relative rate technique Using the literature rate constants for O(3P) + isobutene, cis and trans-2-butene, 3