𝔖 Bobbio Scriptorium
✦   LIBER   ✦

An ESR study of trapped radicals from the gas-phase thermolysis of dialkyl peroxides

✍ Scribed by K.A. Sahetchian; C. Chachaty; R. Rigny; A. Heiss; N. Blin

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
427 KB
Volume
134
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

ESR spin-trap study of radicals present
ESR spin-trap study of radicals present during the thermolysis of some di-tert-alkyl peroxides
✍ Pierre G. Mekarbane; Brian J. Tabner πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 231 KB πŸ‘ 2 views

The thermolysis mechanism of di-tert-butyl and di-tert-amyl peroxide was investigated in a variety of solvents employing electron spin resonance in collaboration with the spin-trapping technique. The tert-amyloxyl radical was trapped for the Ðrst time during the thermolysis of di-tert-amyl peroxide.

ESR study of the radicals obtained from
ESR study of the radicals obtained from adducts of dialkyl itaconates with bromotrichloromethane
✍ Akikazu Matsumoto πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 252 KB πŸ‘ 1 views

Three kinds of bromides were prepared from the reaction of dialkyl itaconates with bromotrichloromethane as precursors of analogous radicals for the propagating radicals of some dialkyl itaconates, i.e., the methyl, deuterated methyl, and adamantyl ester derivatives. The radicals were generated by p

ESR spin-trap study of the radicals pres
ESR spin-trap study of the radicals present during the thermolysis of some bis(tert-alkylperoxy)alkanes and bis(tert-alkylperoxy)cycloalkanes
✍ Pierre G. Mekarbane; Brian J. Tabner πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 175 KB πŸ‘ 2 views

The thermolysis of three bis(tert-alkylperoxy)alkanes and two 1,1-bis(tert-alkylperoxy)cycloalkanes was undertaken at various temperatures between 333 and 383 K and the radicals generated trapped employing DMPO, DEPMPO, PBN-d 14 and TTBNB. The appropriate tert-alkoxyl radical was trapped during the