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ESR spin-trap study of the radicals present during the thermolysis of some novel dialkyl peroxides

✍ Scribed by Pierre G. Mekarbane; Brian J. Tabner


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
167 KB
Volume
39
Category
Article
ISSN
0749-1581

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ESR spin-trap study of radicals present
✍ Pierre G. Mekarbane; Brian J. Tabner πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 231 KB πŸ‘ 1 views

The thermolysis mechanism of di-tert-butyl and di-tert-amyl peroxide was investigated in a variety of solvents employing electron spin resonance in collaboration with the spin-trapping technique. The tert-amyloxyl radical was trapped for the Ðrst time during the thermolysis of di-tert-amyl peroxide.

ESR spin-trap study of the radicals pres
✍ Pierre G. Mekarbane; Brian J. Tabner πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 175 KB πŸ‘ 1 views

The thermolysis of three bis(tert-alkylperoxy)alkanes and two 1,1-bis(tert-alkylperoxy)cycloalkanes was undertaken at various temperatures between 333 and 383 K and the radicals generated trapped employing DMPO, DEPMPO, PBN-d 14 and TTBNB. The appropriate tert-alkoxyl radical was trapped during the