The thermolysis mechanism of di-tert-butyl and di-tert-amyl peroxide was investigated in a variety of solvents employing electron spin resonance in collaboration with the spin-trapping technique. The tert-amyloxyl radical was trapped for the Γrst time during the thermolysis of di-tert-amyl peroxide.
β¦ LIBER β¦
ESR spin-trap study of the radicals present during the thermolysis of some novel dialkyl peroxides
β Scribed by Pierre G. Mekarbane; Brian J. Tabner
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 167 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0749-1581
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The thermolysis of three bis(tert-alkylperoxy)alkanes and two 1,1-bis(tert-alkylperoxy)cycloalkanes was undertaken at various temperatures between 333 and 383 K and the radicals generated trapped employing DMPO, DEPMPO, PBN-d 14 and TTBNB. The appropriate tert-alkoxyl radical was trapped during the