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An ESR study of electron loss and electron capture by silver (I) ions in methyl cyanide

✍ Scribed by Martyn C.R. Symons; D.Robert Brown; George W. Eastland

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 343 KB
Volume: 61
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)85093-9

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✦ Synopsis

Exposure of solutions of siber (I) perchlorate m mcthl I eanidr to 6OCo y-rays ilt 77 I; gave _ag(iI) and Ag(O) ccntrrs in addition to radial-formed from the solvent. Their ESR spectra shoved h>prrfine fcaturrs from Io9_Ag and I*'&! together \*ith features from tburequivaknt 14N nuclei The results arc cxwarasted rti:f~ those prrtiously rcportcd for sofurions of sthrr (I) nitrate in mrthyl oanidr. t\hich gwc Ag(II) and _&g(O) cznfrcs v.hose E!3R spectra \xere devoid of &ny "S hvuerfine fsatwcr -_ I_ introduction We have recentty shown tht exposure of frozen solutions ofsifver nitrate in methyl cyanide to 60co y-rays at 77 K results in the formation of A&I) and As(O) ccntrcs [I 1. together with radicals derhed

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