An equilibrium between carbene and a metal-carbene complex. Homogeneous catalysis by mercury(II)
✍ Scribed by Lambert, Joseph B.; Mueller, Paul H.; Gaspar, Peter P.
- Book ID
- 126145581
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 315 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The first examples of insertion of a CC bond of an alkyne into a C~carbene~C~__α__~ single bond of a carbene complex (CC~__α__~ insertion) are reported. (__prim‐__Alkyl)carbene complexes [(OC)~5~MC(OEt)CH~2~R] (1 a–f; M=Cr, W; R=__n__Pr, C~7~H~7~, Ph) undergo CC~__α__~ insertion of