𝔖 Bobbio Scriptorium
✦   LIBER   ✦

An equilibrium between carbene and a metal-carbene complex. Homogeneous catalysis by mercury(II)

✍ Scribed by Lambert, Joseph B.; Mueller, Paul H.; Gaspar, Peter P.


Book ID
126145581
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
315 KB
Volume
102
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The First Example of an Equilibrium betw
✍ Pablo González-Herrero; Birgit Weberndörfer; Kerstin Ilg; Justin Wolf; Helmut We 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB 👁 2 views

## Dedicated to Professor Herbert W. Roesky on the occasion of his 65th birthday By attempting to generate a cationic, possibly solvated, vinylideneruthenium(ii) complex with a 14-electron configuration at the metal center, we recently found that the reaction of the starting material 1 with HBF 4

CCα Insertion: Insertion of an Alkyne in
✍ Seda Ünaldi; Rudolf Aumann; Roland Fröhlich 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB 👁 1 views

## Abstract The first examples of insertion of a CC bond of an alkyne into a C~carbene~C~__α__~ single bond of a carbene complex (CC~__α__~ insertion) are reported. (__prim‐__Alkyl)carbene complexes [(OC)~5~MC(OEt)CH~2~R] (1 a–f; M=Cr, W; R=__n__Pr, C~7~H~7~, Ph) undergo CC~__α__~ insertion of