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An EPR study of monomeric and dimeric radical cations of 2,5-dimethyl-2,4-hexadiene and 2,7-dimethyl-2,4,6-octatriene

โœ Scribed by L.S. Prasad; R.S. Ding; H.-Q. Wang; E.G. Bradford; L.D. Kispert

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
477 KB
Volume
151
Category
Article
ISSN
0009-2614

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โœ Beth-Ellen Brauer; Marion C. Thurnauer ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 668 KB

In order to study radical cation rearrangements, the species generated by y-irradiation of 1,2-diphenyl-3,3,4,4-tetramethylcyclobutene (CB) and 3,4-diphenyl-2,5-dimethyl-2,4-hexadiene (BD) in frozen Freon solutions were studied by monitoring their EPR and visible absorption spectra. The optical and