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An Electronic Mechanism of Addition Reactions

✍ Scribed by SINGH, LAKHBIR


Book ID
109596232
Publisher
Nature Publishing Group
Year
1958
Tongue
English
Weight
206 KB
Volume
181
Category
Article
ISSN
0028-0836

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πŸ“œ SIMILAR VOLUMES


An elimination-addition mechanism for so
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For the reactions of RPtOl(flHBut)Cl with PrtNH and ButNHz in CHy222, relative rates and product ratios suggest an eliminatiokaddition mechanism with a reartive fmonomerici metaphosphonimidate intermediate.

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Vmylacetylene 1 undergoes reactions with dienopNles by a mechanism involving initial addition of acids to the triple bond, cycloaddition, and elimination of add. For more than half a century the fact that vinylacetylenes can undergo cycloaddition reaclions with dienophiles ("dehydro Die&Alder reacti

Free radical substitution reactions of p
✍ Glen A Russell; Preecha Ngoviwatchai πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 190 KB

Sumary: Phenylacetylenes (PhCXQ with Q = PhS02, I, SPh, 8u3Sn PhC$Hg) undergo free radical chain substitution reactions with RHgCl, R2Hg, (Et0)2P(O)HgCl, (PhS)2Hg or (PhS02)2Hg. The relative reactivities of PhCXQ towards c-C6HII\* are Q = PhS02 (65) > I (19) > Bu3Sn (1.0).