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An electron impact study of HCN elimination from indolizine by use of 13C labelling

✍ Scribed by Madeleine Corval; Marie-France Lautié

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
408 KB
Volume
18
Category
Article
ISSN
1076-5174

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✦ Synopsis

The study of the loss of HCN €rom the molecular ions of [1-13C]-, [2-"C]-and [3-13C]-indolizine shows that, if the C-3 atom is eliminated predominantly, as may be expected, the C-2 atom, and (a) carbon atom(s) of the hexagonal ring are also involved. The losses of "CCH,' and GH,' from the [M-H"CN]" ions of the three compounds point to the interference of distinct mechanisms of HCN elimination, leading to different structures for the [C,&]+. ions.

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