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An Efficient Synthetic Scheme for Natural α-Conotoxins and Their Analogues

✍ Scribed by M. N. Zhmak; I. E. Kasheverov; Yu. N. Utkin; V. I. Tsetlin; O. M. Vol'pina; V. T. Ivanov

Book ID: 110299876
Publisher: SP MAIK Nauka/Interperiodica
Year: 2001
Tongue: English
Weight: 50 KB
Volume: 27
Category: Article
ISSN: 1068-1620
DOI: 10.1023/a:1011319101676

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## Abstract The Friedel‐Crafts alkylation of indoles with nitroacrylates could provide __α__‐ and __β__‐tryptophan nitro‐precursors, respectively, in moderate to good yields under Lewis acid catalysis. The diastereoselectivities of the reaction were enhanced by using 2‐substituted indoles. The alky