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An Efficient Synthesis of cis-Jasmone

✍ Scribed by Büchi, G.; Wüest, H.


Book ID
118742244
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
283 KB
Volume
31
Category
Article
ISSN
0022-3263

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## Abstract An efficient synthesis of methyl (±)‐jasmonate and (__Z__)‐jasmone is described. The Key step is a phase‐transfer reaction between cyclopentane (**9**) and 1, 4‐dibromo‐2‐pentene (**6a/b**) to give the spiro [2.4]hepten‐4‐ones **4a** and **4b**.