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An Efficient Synthesis of Methyl (±)-Jasmonate and (Z)-Jasmone

✍ Scribed by Ferdinand Näf; René Decorzant

Publisher
John Wiley and Sons
Year
1978
Tongue
German
Weight
341 KB
Volume
61
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

An efficient synthesis of methyl (±)‐jasmonate and (Z)‐jasmone is described. The Key step is a phase‐transfer reaction between cyclopentane (9) and 1, 4‐dibromo‐2‐pentene (6a/b) to give the spiro [2.4]hepten‐4‐ones 4a and 4b.

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