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An efficient stereospecific total synthesis of (±) terrein

✍ Scribed by A.J.H. Klunder; W. Bos; B. Zwanenburg


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
238 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis


Flash vacuum pyrolysis of functionalized tricyclo15.2.1.02r6 ldecenone epoxide 2, and acetals 3 and 4 affords cyclopentadienone epoxide6 and -. acetals 10 and 8, respectively.

These epoxides are suitable precur-__

AN EFFICIENT STEREOSPECIFIC TOTAL SYNTHESIS OF (?) TERREIN


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Stereospecific total synthesis of cycloe
✍ Edward Y. Chen 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 226 KB

A stereospecific sequence from the allylic alcohol 3 to the new anti-biotic, cycloeudesmol 2, in 9 steps (21.7% overall yield) is described.