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An efficient route to heteroarene-substituted vinyl- and allyl-silanes via palladium-phosphine complex catalyzed cross-coupling

✍ Scribed by Akio Minato; Keizo Suzuki; Kohei Tamao; Makoto Kumada

Book ID
104242344
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
222 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

Heteroarene-substituted vinyl-and allyl-silanes were obtained in good yields by the cross-coupling reaction of either heteroaryl Grignard reagents with halovinyl-and haloallyl-silanes or, alternatively, silyl-and

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An efficient route to 4-substituted coum
An efficient route to 4-substituted coumarins, 2(5H)-furanones, and pyrones via palladium-catalyzed couplings of alkenyl tosylates with organoindium reagents
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Highly efficient palladium-catalyzed couplings of alkenyl tosylates with organoindium reagents under mild conditions are described, which give rise to 4-substituted coumarins, 2(5H)-furanones, and pyrones in good to excellent yields.

ChemInform Abstract: An Efficient Route
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