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An efficient Rh-catalyst system for the intramolecular [4+2] and [5+2] cycloaddition reactions

✍ Scribed by Bin Wang; Ping Cao; Xumu Zhang

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 94 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01432-5

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✦ Synopsis

A new Rh-catalyst system has been developed for the [4+2] and [5+2] cycloaddition reactions. This new system shows high reactivity at room temperature and the Rh-center bears tunable phosphine ligands. Up to 1000 turnovers have been obtained for the [4+2] cycloaddition reaction at room temperature.

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