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An efficient protocol for the reduction of ketones with tin(II) complexes and PMHS

✍ Scribed by Nicholas J Lawrence; Simon M Bushell

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 180 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)00652-3

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✦ Synopsis

A mixture of tin(II) tri¯ate/pybox and polymethylhydrosiloxane (PMHS) in methanol eects the ecient reduction of ketones; the use of an enantiomerically pure pybox ligand leads to moderate enantioselectivity.

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