An Efficient Hydrogenation of Dinitrile to Aminonitrile in Supercritical Carbon Dioxide
β Scribed by Maya Chatterjee; Masahiro Sato; Hajime Kawanami; Toshirou Yokoyama; Toshishige Suzuki; Takayuki Ishizaka
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 234 KB
- Volume
- 352
- Category
- Article
- ISSN
- 1615-4150
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Iridium-Catalyzed Enantioselective Hydrogenation of Imines in Supercritical Carbon Dioxide. -Supercritical CO 2 is used as an environmentally benign alternative solvent for the enantioselective hydrogenation of prochiral imines. Main advantages of this reaction medium are the low catalyst loading,
## Abstract For Abstract see ChemInform Abstract in Full Text.
One way of collecting extracted analytes after a supercritical fluid extraction (SFE) is to pass the depressurized fluid through a trap composed of a solid adsorbent. The influence of the adsorbent nature on the trap efficiency has been studied. First, the retention factors of each compound of a pol
A new "CO2-philic" chiral rhodium diphosphinite complex was synthesized and applied as catalyst precursor in the asymmetric hydrogenation of dimethyl itaconate in scCO2, scC2H6 and various liquid organic solvents. Deuterium labeling studies and parahydrogen-induced polarization (PHIP) NMR experiment