An Efficient CuCN-Catalyzed Synthesis of Optically Active 2,3-Allenols from Optically Active 1-Substituted 4-Chloro-2-butyn-1-ols
โ Scribed by Li, Jing; Kong, Wangqing; Fu, Chunling; Ma, Shengming
- Book ID
- 126076421
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 332 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
The fn'st synthesis of several types of optically active l,l,2-lrifluoro-1alkea-3-ols has been accomplished through the Pseudomonas cepacia F~ase-catalyzed trans-esterif~ation. The PCL catalyzed acylation using vinyl chloroacetate as the aeyl donor provided the corresponding fiuorinated-allyl alcoho
Treatment of (-)-O-acyllactamides or mandelamides with TBSOTf in the presence of base gives optically active 2-oxy-1,3-oxazolidin-4-ones stereoselectively, which serve as useful precursors for the preparation of optically active secondary 2-pyrrolidones via radical cyclization and subsequent one-ste