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An Efficient Chiral Phosphitooxazoline Ligand for Pd-Catalyzed Asymmetric Allylic Sulfonylation.

✍ Scribed by Oleg G. Bondarev; Sergey E. Lyubimov; Alexei A. Shiryaev; Nikolay E. Kadilnikov; Vadim A. Davankov; Konstantin N. Gavrilov


Publisher
John Wiley and Sons
Year
2003
Weight
108 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract Novel __P__\*‐chiral __P__,__N__‐bidentate ligands were synthesized by treatment of ferrocene‐based imino alcohols with chlorophosphites derived from (__S__)‐2‐anilinomethylpyrrolidine or (__S__)‐prolinol. Metal chelate complexes with the ligands – [Rh(CO)(PN)Cl] and [Pd(PN)(allyl)]^+^X