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An efficient asymmetric synthesis of the four stereoisomers of 3-hydroxyleucine

✍ Scribed by Toshiaki Sunazuka; Tohru Nagamitsu; Haruo Tanaka; Satoshi Ōmura; Paul A. Sprengeler; Amos B. Smith III

Book ID
103408699
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
152 KB
Volume
34
Category
Article
ISSN
0040-4039

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A practical new asymmetric synthesis of
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✍ Karl J. Hale; Soraya Manaviazar; Vern M. Delisser 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 552 KB

Abstmctz A convenient new asymmetric synthesis of both enaatiomcrs of eryrhro-3-hydroxylcuciae is desctibed. The key steps involve Sharpless asymmetric dihydroxylation (AD) of a&unsaturated ester 3, cyclic sulphate formation from the resulting diol, SNZ reaction with sodium azide, deesterification w