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An efficient and robust fluoroketone catalyst epoxidation

✍ Scribed by Julien Legros; Benoı̂t Crousse; Jack Bourdon; Danièle Bonnet-Delpon; Jean-Pierre Bégué

Book ID
104230816
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
77 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

The fluoroalkylketone 2 is an efficient catalyst in the epoxidation reaction using Oxone ® as oxidant. In hexafluoro-2propanol (HFIP), the ketone can be used in a catalytic amount (1 or 5 mol%) with only 1.5 equiv. of Oxone ® . The reaction gave good yields of epoxides for a number of olefin substrates, included low reactive ones.

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