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Electrogenerated Polymers as Efficient and Robust Heterogeneous Catalysts for the Hydrolytic Kinetic Resolution of Terminal Epoxides

✍ Scribed by Xiang Hong; Dr. Mohamed Mellah; Franck Bordier; Dr. Régis Guillot; Dr. Emmanuelle Schulz

Book ID
112019331
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
464 KB
Volume
4
Category
Article
ISSN
1867-3880

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Polyglycerol-Supported Co- and Mn-salen
Polyglycerol-Supported Co- and Mn-salen Complexes as Efficient and Recyclable Homogeneous Catalysts for the Hydrolytic Kinetic Resolution of Terminal Epoxides and Asymmetric Olefin Epoxidation
✍ Maryam Beigi; Sebastian Roller; Rainer Haag; Andreas Liese 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 291 KB 👁 1 views

## Abstract In this report we demonstrate the suitability of hyperbranched polyglycerol as high‐loading support for asymmetric catalysis. A polyglycerol‐supported unsymmetrical salen ligand was prepared and purified by means of ultrafiltration. The polymeric ligand was metalated with cobalt acetate