## Abstract Aqueous hydrochloric acid proved to be a very reliable modulator for adjusting the reactivity of palladium on carbon. Thus an efficient and practical method for the highly chemoselective hydrogenation of __N,N__βdialkylnitrobenzylamines to aminoβ__N,N__βdialkylbenzylamine hydrochlorides
An Efficient and Practical Method for Highly Chemoselective Hydrogenation of Nitrobenzylamines to Aminobenzylamine Hydrochlorides.
β Scribed by Chuanjie Cheng; Xinyan Wang; Lixin Xing; Bo Liu; Rui Zhu; Yuefei Hu
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 33 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The reaction of alkylidenecyclopropanes with HCl or with HBr proceeds very smoothly at 120Β°C to produce the corresponding homoallylic halides stereoselectively in good to excellent yields. For example, the reaction of (1-phenylbenzylidene)cyclopropane, (1-butylpentylidene)cyclopropane and octylidene
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