✦ LIBER ✦

An Efficient and Practical Method for Highly Chemoselective Hydrogenation of Nitrobenzylamines to Aminobenzylamine Hydrochlorides

✍ Scribed by Chuanjie Cheng; Xinyan Wang; Lixin Xing; Bo Liu; Rui Zhu; Yuefei Hu

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 113 KB
Volume: 349
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200600521

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✦ Synopsis

Abstract

Aqueous hydrochloric acid proved to be a very reliable modulator for adjusting the reactivity of palladium on carbon. Thus an efficient and practical method for the highly chemoselective hydrogenation of N,N‐dialkylnitrobenzylamines to amino‐N,N‐dialkylbenzylamine hydrochlorides was established. The method features convenient performance, easy work‐up and high efficiency.

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