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An Efficient and General Synthesis of Furan-2-acetic Esters by Palladium-Catalyzed Oxidative Carbonylation of ( Z )-2-En-4-yn-1-ols

✍ Scribed by Gabriele, Bartolo; Salerno, Giuseppe; De Pascali, Francesca; Costa, Mirco; Chiusoli, Gian Paolo


Book ID
127377022
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
177 KB
Volume
64
Category
Article
ISSN
0022-3263

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Novel synthesis of furan-2-acetic esters
✍ Bartolo Gabriele; Giuseppe Salerno; Francesca De Pascali; Giuseppe Tomasi ScianΓ² πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 185 KB

Furan-2-acetic esters are obtained in good yields by direct oxidative cyclization-alkox~.'carbonylation of (Z)-2-en-4-yn-l-ols. bearing both an alkyl or an aD'l substituent a to the hydrox3' group, in the presence of catalytic amounts of palladium iodide in conjunction with potassium iodide at 50-70