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An efficient and enantioselective total synthesis of naturally occurring L-783277

✍ Scribed by Hwan Geun Choi; Jung Beom Son; Dong-Sik Park; Young Jin Ham; Jung-Mi Hah; Taebo Sim


Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
844 KB
Volume
51
Category
Article
ISSN
0040-4039

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An Enantioselective Total Synthesis of N
✍ Wolfgang Oppolzer; Martin Petrzilka πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 497 KB

## Abstract The naturally occurring Lycopodium alkaloid (+)‐luciduline (**1**) has been synthesized from (__R__)‐5‐methyl‐cyclohex‐2‐en‐1‐one (**12**) by a sequence of seven steps (s. __Scheme 6__) in 33% overall yield. The key step **4β†’6** presumably involves a transient nitrone **5** which underg