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An effective method for the selective synthesis of geminal diacetates (acylals) from aromatic aldehydes using alumina-supported InCl3

✍ Scribed by Masoud Salavati-Niasari; Samansa Hydarzadeh


Book ID
108211525
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
123 KB
Volume
237
Category
Article
ISSN
1381-1169

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πŸ“œ SIMILAR VOLUMES


An efficient method for the chemoselecti
✍ Marc D Carrigan; Kyle J Eash; Matthew C Oswald; Ram S Mohan πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 218 KB

Aromatic aldehydes are smoothly converted into the corresponding acylals in good yields in the presence of 0.10 mol% Bi(OTf) 3 β€’xH 2 O. Ketones are not affected under the reaction conditions. The highly catalytic nature of bismuth triflate and the fact that it is relatively non-toxic, easy to handle