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An Easy Synthetic Route to Hexakis(6-O-benzoyl)-α-cyclodextrin
✍ Scribed by Cuzzola, Angela; Menicagli, Rita; Salvadori, Piero
- Book ID
- 126773587
- Publisher
- Taylor and Francis Group
- Year
- 1998
- Tongue
- English
- Weight
- 377 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0039-7911
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## Abstract Hexakis(2,3‐di‐__O__‐methyl)‐α‐cyclodextrin was treated with 2,4‐dimethoxybenzene‐1,5‐disulfonyl chloride to give 6^A^,6^B^‐di‐__O__‐sulfonated product 5 in only a 3.0% yield. When treated with sodium __p__‐allyloxyphenoxide, 5 gave 6^A^,6^B^‐(bis‐__O__‐__p__‐allyloxyphenyl)hexakis(2,3‐
A synthesis of amphiphilic per(2,3-di-O-alkyl)-a-and b-cyclodextrins and hexakis(6-deoxy-6-thio-2,3di-O-pentyl)-a-cyclodextrin and their monolayer behavior on a water surface is presented. Long alkyl chains were introduced by a treatment of the per(6-O-tert-butyldimethylsilyl) derivatives with an ap