An Easy and Practical Synthetic Route to Electron Rich Water Soluble Ligands: α-Aminomethylation of Trishydroxymethylphosphine

ChemInform Abstract: Water Soluble Phosp

ChemInform Abstract: Water Soluble Phosphanes. Part 9. Nucleophilic Phosphanylation of Fluoroaromatic Compounds with Carboxyl, Carboxymethyl, and Aminomethyl Functionalities — An Efficient Synthetic Route to Amphiphilic Arylphosphanes.

✍ M. HINGST; M. TEPPER; O. STELZER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

In continuation of a work to develop water-soluble phosphanes for two-phase catalysis, nucleophilic phosphanylations of potassium or lithium salts of fluoroaromatic compounds are carried out. Ligands such as (III)-(VI) and (VIII) and (X) are characterized by NMR and mass spectroscopy. -(HINGST, M.;